Titre : The electron-poor vinylcyclopropanes in organometallic catalysis: interesting skeletons with various reactivities 

Auteurs : Maxime Laugeois, Maxime Vitale, Véronique Michelet, Virginie Ratovelomanana-Vidal,  

Revue : Catalysis by Transition Metals 

Numéro : Issue 1 

Volume : 1 

Date : 2019/03/27 

DOI :  

ISSN :  

Résumé : Vinylcyclopropanes are molecules with extremely rich reactivity and among these, the electron-deficient vinylcyclopropanes have a "donor-acceptor" type polarization which gives them a particular reactivity. This article presents on the one hand the main routes of synthesis of electron-deficient vinylcyclopropanes under stoichiometric and catalytic conditions. On the other hand, the reactivity of the vinylcyclopropanes is presented in the presence of homogeneous organometallic catalysts: the rearrangement processes, functionalization reactions via ring opening and catalytic (3 + 2) cycloaddition reactions. 

Éditeur : ISTE OpenScience