TY - Type of reference TI - The electron-poor vinylcyclopropanes in organometallic catalysis: interesting skeletons with various reactivities AU - Maxime Laugeois AU - Maxime Vitale AU - Véronique Michelet AU - Virginie Ratovelomanana-Vidal AB - Vinylcyclopropanes are molecules with extremely rich reactivity and among these, the electron-deficient vinylcyclopropanes have a "donor-acceptor" type polarization which gives them a particular reactivity. This article presents on the one hand the main routes of synthesis of electron-deficient vinylcyclopropanes under stoichiometric and catalytic conditions. On the other hand, the reactivity of the vinylcyclopropanes is presented in the presence of homogeneous organometallic catalysts: the rearrangement processes, functionalization reactions via ring opening and catalytic (3 + 2) cycloaddition reactions. DO - JF - Catalysis by Transition Metals KW - vinylcyclopropane, electron-deficient, catalysis, rearrangment, cycloaddition, vinylcyclopropane, électro-appauvri, catalyse, réarrangement, cycloaddition, L1 - http://www.openscience.fr/IMG/pdf/iste_cmt19v1n1_2.pdf LA - en PB - ISTE OpenScience DA - 2019/03/27 SN - TT - Les vinylcyclopropanes électro-appauvris en catalyse organométallique – des molécules aux réactivités plurielles UR - http://www.openscience.fr/The-electron-poor-vinylcyclopropanes-in-organometallic-catalysis-interesting IS - Issue 1 VL - 1 ER -